When you just launch the explorer shell it launches with Libraries as active path as shown below:
You can have the explorer open with a specified path/folder as shown below:
%SystemRoot%explorer.exe explorer.exe /root,C:TempTest
You can also have explorer open with a default path along with a selection made on one of the sub-item file/folder as shown below
%SystemRoot%explorer.exe explorer.exe C:TempTestTemp1,/select
<p><a href="http://gunnalag.files.wordpress.com/2011/10/image2.png"><img style="background-image:none;border-bottom:0;border-left:0;padding-left:0;padding-right:0;display:inline;border-top:0;border-right:0;padding-top:0;" title="image" border="0" alt="image" src="http://gunnalag.files.wordpress.com/2011/10/image_thumb2.png" width="600" height="446" /></a>