CSVDE is a command that can be used to import and export objects to and from the AD into a CSV-formatted file. A CSV (Comma Separated Value) file is a file easily readable in Excel. I will not go to length into this powerful command, but I will show you some basic samples of how to import a large number of users into your AD. Of course, as with the DSADD command, CSVDE can do more than just import users.
LDIFDE is a command that can be used to import and export objects to and from the AD into a LDIF-formatted file. A LDIF (LDAP Data Interchange Format) file is a file easily readable in any text editor, however it is not readable in programs like Excel. The major difference between CSVDE and LDIFDE (besides the file format) is the fact that LDIFDE can be used to edit and delete existing AD objects (not just users), while CSVDE can only import and export objects
Reference: http://wiki.answers.com/Q/What_is_the_difference_between_ldifde_and_csvde#ixzz1hSmfLiJe